With Barcelona, Pizzi won the Spanish Supercup in 1996, the UEFA Super Cup and Spanish Cup in 1997, conquering the latter again in the following year while also winning his only league title. Arguably, his most memorable moment was the decisive goal in the 5–4 home win over Atlético Madrid in the domestic cup's quarter-finals second leg, after the Blaugrana trailed 0–3 at half-time.