In November 2002, Olivia Harrison produced the Concert for George tribute, which featured Eric Clapton, Jeff Lynne, Billy Preston, Tom Petty, Shankar, Starr and McCartney, along with Dhani. Held at London's Royal Albert Hall and filmed by director David Leland, the event was presented under the auspices of George's Material World Foundation; all proceeds from the concert and subsequent album, film and book releases went to the foundation for dispersal to charities that he and the family supported. Harrison's video production for the Concert for George film received the Grammy Award for Best Long Form Music Video in 2005. She wrote the introduction to the 2002 reissue of George's autobiography, I, Me, Mine, and authored the book Concert for George, which was published by Genesis Publications in 2005.
As of 2002, Harrison's 1990 Romanian Angel initiative was still active. In May 1990, before the release of the fundraising single and album, ten trucks filled with food, medical supplies and clothing, together with 32 aid workers, were dispatched to Romania. According to Harrison, all the funds raised by the appeal went directly to the cause, as the administrative costs were paid for by her and the other RAA founders. In September 2000, she and George met with local representatives to monitor the progress of the RAA-funded programs for orphanage sanitation and professional staff.