In January 2014, Pogba was named by The Guardian as one of the ten most promising young players in Europe. On 20 February, Pogba scored his first goal in UEFA club competitions as Juventus defeated Trabzonspor 2–0 at home in the first leg of the round of 32 of the 2013–14 UEFA Europa League. On 14 April, Pogba produced an assist in Juventus's 2–0 win over Udinese, the same team that Pogba scored two magnificent goals against in the previous season. Later that week, Pogba scored the only goal in Juventus's 1–0 win over Bologna. Pogba was also named the man of the match for his performance. Pogba would prove to be a key player for the club that season, breaking into the starting line-up, and making more appearances (51) for the club than any other player across all competitions that season, also scoring 9 goals. He finished the season with his second consecutive Serie A title under manager Antonio Conte, also reaching the semi-finals of the Europa League.
On 20 September 2014, under new Juventus manager Massimiliano Allegri, Pogba contributed to Juventus's away win against Milan by providing the assist for the only goal of the game, scored by Carlos Tevez. Later that month, on 18 October, Pogba saved Juventus from a defeat against Sassuolo by scoring a decisive equaliser; he was later named Man of the Match. On 24 October, Pogba renewed his contract with Juventus, tying him to the club until 2019. On 4 November, on his 100th appearance with the club, Pogba scored Juventus's third goal against Olympiacos in the Champions League, helping them to win the match; this was his first ever Champions League goal. On 22 November, he scored his first brace of the season in a 3–0 win against Lazio at the Stadio Olimpico in Rome. On 28 October, Pogba was named as one of the 23 shortlisted candidates for the 2014 Ballon d'Or; at 21, he was the youngest on the list. In 2014, Pogba was awarded the Bravo Award, by the Italian sports magazine Il Guerin Sportivo, which is awarded to the best under-23 player who has participated in European competitions.
On 6 June 2014, Pogba was named in France's squad for the 2014 FIFA World Cup. On 15 June, he started in central midfield in the team's first World Cup fixture – a 3–0 victory over Honduras – suffering a foul from Wilson Palacios which led to a red card for the Honduran and a penalty kick, which was converted by Karim Benzema to give France the lead. He appeared as a substitute in the team's second match, assisting a goal for Benzema in a 5–2 victory of Switzerland. In the round of 16, Pogba scored a 79th minute opening goal and was named man of the match by FIFA as Les Bleus defeated Nigeria 2–0 in Brasília. France were eliminated in the quarter-finals of the competition following a 1–0 defeat to eventual champions Germany on 4 July with Pogba giving away the free kick from which the Germans eventually scored. On 13 July 2014, Pogba was named the tournament's Best Young Player.