Having rebounded from his injuries, in 1933 Martin was leading the league in hitting with a .363 batting average in the middle of June, earning him a starting role as the third baseman for the National League team in the inaugural Major League Baseball All-Star Game held on July 6, 1933. Now hitting as the Cardinals' leadoff hitter, he finished the season ranked sixth in the league with a career-high .316 average and led the league with 122 runs scored and 26 stolen bases. Martin ranked tenth in the league with a .456 slugging percentage, and he had a career-high .387 on-base percentage along with 36 doubles, 12 triples and eight home runs as the Cardinals improved to a fifth-place finish. He came in fifth place in the voting results for the 1933 National League Most Valuable Player Award.
In a 13-year major league career, Martin played in 1,189 games, accumulating 1,227 hits in 4,117 at bats for a .298 career batting average along with 756 runs, 270 doubles, 75 triples, .443 slugging percentage, 59 home runs, 501 runs batted in, 146 stolen bases, 369 bases on balls and an on-base percentage of .358. He retired with a .973 career fielding percentage in 613 games as an outfielder and a .927 fielding percentage in 429 games as a third baseman. A four-time All-Star, Martin's World Series career batting average of .418 (23-for-55) is still a series record, and he is tied for 10th with seven World Series stolen bases. He led the National League three times in stolen bases and once in runs scored. On May 5, 1933, Martin hit for the cycle in a game against the Philadelphia Phillies at the Baker Bowl.